Thermal Degradation of Terpolymer Derived from 2, 4-dihydroxyacetophenone, propylenediamine and Formaldehyde

Manisha M. Jiwatode; Kiran P. Kariya; Baliram. N. Berad

Thermal Degradation of Terpolymer Derived from 2, 4-dihydroxyacetophenone, propylenediamine and Formaldehyde

Authors

Manisha M. Jiwatode Department of Chemistry, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur, India
Kiran P. Kariya Department of Chemistry, VMV Commerce JMT Arts & JJP Science College, Nagpur, India
Baliram. N. Berad Department of Chemistry, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur, India

Keywords:

synthesis, characterization, conductometric titration, intrinsic viscosity, Freeman Carroll and Sharp-Wentworth methods and Antibacterial activities

Abstract

The terpolymer (2,4-DHAPrDF) was synthesized by condensation of 2,4-dihydroxyacetophenone and paraphenylene diamine with formaldehyde in the presence of 2 M HCl as a catalyst at 130 ± 2 ^OC for 5 h. The terpolymer 2,4-DHAPrDF was characterized by elemental analysis FTIR, ¹HNMR and UV-Visible spectroscopy. The thermal decomposition behavior 2,4-DHAPrDF was studied using thermogravimetric analysis (TGA/DTA) in a static oxygen atmosphere at a heating rate 10 ^OC /min. Freeman-Carroll, Sharp-Wentworth methods were used to calculate thermal activation energy (Ea), the order of reaction (n), entropy change (ΔS) Synthesized terpolymer resin shown moderate antibacterial activity and porous morphology.

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Published

2017-06-25

How to Cite

Manisha M. Jiwatode, Kiran P. Kariya, & Baliram. N. Berad. (2017). Thermal Degradation of Terpolymer Derived from 2, 4-dihydroxyacetophenone, propylenediamine and Formaldehyde. World Journal of Pharmaceutical Sciences, 5(7), 51–60. Retrieved from https://wjpsonline.com/index.php/wjps/article/view/thermal-degradation-terpolymer